We consider an Eulerian-Lagrangian localized adjoint method
(ELLAM) applied to nonlinear model equations governing solute
transport and sorption in porous media. Solute transport in the
aqueous phase is modeled by standard advection and hydrodynamic
dispersion, while two types of solid phase are distinguished --- a
fraction which achieves equilibrium with the aqueous phase
quickly, and another which does not. The rapidly sorbing fraction
is modeled using a local equilibrium assumption, while a
first-order rate expression is used for the slowly sorbing
fraction. The presence of both equilibrium and non-equilibrium
sorption can be challenging for Eulerian-Lagrangian methods, since
information may propagate along different characteristic
directions in the space-time domain.
Here, we present an implementation of a finite element ELLAM
(FE-ELLAM) discretization in both fully coupled and operator-split
frameworks for the reactive transport model. We then evaluate our
method for several test problems spanning a range of auxiliary and
physical conditions and compare its performance to more standard
approaches.
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